PROBING VIBRATIONAL WAVE PACKETS IN ORGANOPHOSHOROUS MOLECULES USING FEMTOSECOND TIME-RESOLVED MASS SPECTROMETRY

Organic phosphates and phosphonates share a basic structure with organophoshorous chemical warfare agents and cellular components such as DNA. To understand ultrafast nuclear dynamics in isolated organic phosphates and phosphonates, Femtosecond Time Resolved Mass Spectrometry (FTRMS) was employed. FTRMS applies the pump-probe technique with mass spectrometric detection. In our experiment an ionizing $10^{14}$ W cm$^{-2}$, 1500 nm, 18 fs pump and a non-ionizing $10^{13}$ W cm$^{-2}$, 800 nm, 25 fs probe pulse were used. Experiments were performed on four related compounds: dimethyl methylphosphonate (DMMP), diethyl methylphosphonate (DEMP), diisopropyl methylphosphonate (DIMP) and trimethyl phosphate (TMP). The yields of parent molecular ions generated by the pump pulse exhibited ultrafast oscillations with the period depending on the parent molecule. These oscillations indicate the presence of a vibrational wave packet that is excited upon ionization. In DMMP, a well resolved peak of 45 fs ($732\pm28$ cm$^{-1}$) was observed with a weak feature at 610-650 cm$^{-1}$, while DIMP exhibits bimodal oscillation with frequencies of $554\pm28$ and 670-720 cm$^{-1}$. Oscillations for DEMP were barely visible due to rapid decay. The high- and low- frequency oscillations in DMMP and DIMP were assigned to coherent excitation of O-P-O bend and P-C stretching respectively based on DFT calculations. Bimodal oscillations at 770 and 880 cm$^{-1}$ in TMP were also observed and are tentatively assigned to the symmetric and asymmetric P-O stretching modes. These results suggest that this group of compounds exhibits similar coherent vibrational excitation upon ionization. These results may have applications to development of new organophosphorous chemical warfare agent detection and destruction techniques based on the coherent control and may point to reaction pathways in organophosphorous compounds of biological relevance

Electronic support tools for identification and management of rice weeds in Africa for better-informed agricultural change agents

International audienceWe developed an interactive electronic weed identification tool, AFROweeds, and an online network, Weedsbook, for agricultural change agents to aid communication and offer assistance to rice farmers with specific weed problems. We collected quantitative and qualitative data to assess effectiveness and usefulness of these products with potential users. With the online version of AFROweeds, used on an electronic tablet, average weed identification time in the field was 7 min 6 s with 44% successful identifications. Poor mobile network coverage and slow internet were the main reasons for the relative long identification time and low success rate. A second trial was done with the offline version, pre-installed on a tablet. The average identification time was 6 min 34 s, with a success rate of 75%. The online network Weedsbook, established alongside AFROweeds, was assessed by the test users as a useful additional aid, enabling agricultural change agents and agronomists to exchange information or request assistance on all aspects of weeds and weed management. The potential improvements of both products are discussed

A Case of Cyperus spp. and Imperata cylindrica Occurrences on Acrisol of the Dahomey Gap in South Benin as Affected by Soil Characteristics: A Strategy for Soil and Weed Management

Because of the limiting efficacy of common weed control methods on Cyperus spp. and Imperata cylindrica their occurrences in tropical agroecologies and the effect of soil properties in suppressing these species were investigated in south Benin (Cotonou), a typical ecology of the Dahomey gap. Weeds and soil samples were collected twice early and later in the rainy season in 2009 at four topographic positions (summit, upper slope, middle slope, and foot slope). Sampling was done according to Braun-Blanquet abundance indices (3 and 5) and the absence (0) of Cyperus and Imperata in a quadrat, respectively. The relationship between their respective abundances and soil parameters (texture, C, N, P, K, Na, Ca, Mg, and Fe) was explored. Weed occurrence was less related to soil texture, and Imperata growth was more influenced by soil nutrients (K, Ca, and Fe) than Cyperus spp. Soil cation ratios of K : Mg and Ca : Mg were the main factors that could be changed by applying K and/or Mg fertilizers to reduce Cyperus and/or Imperata occurrence. Maintaining high Fe concentration in soil at hillside positions can also reduce Imperata abundance, especially in the Dahomey gap

Weed competitiveness of the lowland rice varieties of NERICA in the southern Guinea Savanna

Weed competition is a major constraint to lowland rice production in West Africa. Interspecific rice varieties named New Rice for Africa (NERICA) may have superior weed competitiveness and could as such play an important role in integrated weed management. The NERICA varieties were developed from the wide cross between high-yielding Oryza sativa (L.) and weed competitive and disease resilient Oryza glaberrima (Steud.). In this study weed competitiveness of all 60 lowland varieties of NERICA (NERICA-L) was compared with their most frequently used parents [IR64 (O. sativa) and TOG5681 (O. glaberrima)], the weed competitive variety Jaya (O. sativa) and the O. glaberrima upland NERICA parent CG14. During the 2006 and 2007 rainy seasons these varieties were grown under weed-free and weedy conditions in a lowland farmers’ field with partially controlled irrigation in south-east Benin. Weedy plots included single hand weeding at 28 days after sowing, whereas weed-free plots were weekly weeded. Most important weed species encountered in this study were Basilicum polystachyon, Alternanthera sessilis, Echinochloa colona, Sorghum arundinaceum, Cyperus halpan and Cyperus rotundus. Average weed-inflicted yield loss across varieties was 39% in 2006 and 8% in 2007. In both years varieties differed significantly in grain yields under weed-free and weedy conditions and in the growth of weed biomass they permitted under weedy conditions, as observed at harvest. None of the lowland varieties of NERICA consistently had stronger weed suppressive ability than TOG5681 across 2 years. Nine varieties of NERICA-L (-6, -32, -35, -37, -42, -53, -55, -58 and -60) were identified with high yields under both weed-free and weedy conditions. These nine NERICA-L varieties, together with Jaya, out-yielded the other 51 NERICA-L varieties as well as IR64 and the two O. glaberrima varieties. Weed-free yield, crop growth duration, and weed biomass at harvest significantly correlated with weedy yield in both years. Interspecific breeding using O. glaberrima appears to be an effective approach for improving yield potential and weed competitiveness of semi-dwarf O. sativa and as such for widening the range of useful varieties for lowland rice farmers in Africa